there are several ways to realise your problem.
First one: You can use a Tabcontrol and apply the BackstageTabcontrolStyle. By modifing the Tabitem.Header you can also change the appearance.
Second one: You can use the RibbonGallery (or sth. like that, is included in the package) and style your own Items
(I hope you meant with listview list like "last used documents" where your documents name and a icon is shown)
I can also post some code, if you want